1-Bromodecane → 5-Benzyloxy-2-(4-decyloxyphenyl)pyrimidine

HRID 2227115Notes

Reaction equation

HRID 2227115 reaction equation
[CH2:1]([O:8][C:9]1[CH:10]=[N:11][C:12]([C:15]2[CH:20]=[CH:19][C:18]([OH:21])=[CH:17][CH:16]=2)=[N:13][CH:14]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32].CC(C)=CCCC1CCC(CCC2C=CC(OCC3CCC(CCCCC)=CC3)=CC=2)CC=1>>[CH2:1]([O:8][C:9]1[CH:14]=[N:13][C:12]([C:15]2[CH:16]=[CH:17][C:18]([O:21][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32])=[CH:19][CH:20]=2)=[N:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 81731-BromodecaneHCID 184718074-[2-(4-(4-Methyl-3-pentenyl)-3-cyclohexenyl)ethyl]-1-(4-pentyl-3-cyclohexenyl)methoxybenzeneHCID 1357441904-[5-(Benzyloxy)pyrimidin-2(1H)-ylidene]cyclohexa-2,5-dien-1-one

Product 1

HCID 184717945-Benzyloxy-2-(4-decyloxyphenyl)pyrimidine

Procedure

The reaction between 5-benzyloxy-2-(4-hydroxyphenyl)pyrimidine (prepared essentially according to the procedure of E. P. Janulis et al., U.S. Pat. No. 5,399,291) and bromodecane is essentially that used for synthesis of ether 2H.

Workup

  1. customprepared essentially

Sources & evidence

ORD record
ord-6e28400805e2472eb1dc17fc3e192c40
Source dataset
uspto-grants-2002_07
Patent number
US06413448B1

Reaction notes

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