HRID2227614

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID13018

Benzene, 1-ethynyl-4-methyl- (9CI)

C9H8

HCID85171

p-Fluorotoluene-alpha-thiol

C7H7FS

HCID5360545

Sodium

PRODUCTS

生成物

$结构：Cc1ccc(/C=C\C(SC(/C=C\c2ccc(C)cc2)c2ccc(F)cc2)c2ccc(F)cc2)cc1$

HCID86588950

未命名化合物

PROCEDURE

实验过程

A solution of 4-methylphenylacetylene (0.02 mol) and 4-fluorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to the General Procedure to form Z-4-methylstyryl 4-fluorobenzylsulfide. The title compound was obtained in 69% yield following oxidation. 1HNMR (CDCl3) δ 2.46 (3H, s), 4.62 (2H, s), 6.78 (1H, d, JH,H=11.98), 7.18-7.59 (9H aromatic+1H ethylenic).