Triethylsilane → HCID 15429138, compound

HRID 2228343Notes

Reaction equation

HRID 2228343 reaction equation
[CH2:1]([OH:6])[CH2:2][CH2:3][CH2:4][OH:5].C(O[CH:10]=[CH2:11])=C.[CH2:12]([SiH:14]([CH2:17][CH3:18])[CH2:15][CH3:16])[CH3:13]>>[CH2:12]([Si:14]([CH2:10][CH3:11])([CH2:17][CH3:18])[CH2:15][CH2:16][O:5][CH2:4][CH2:3][CH2:2][CH2:1][OH:6])[CH3:13]

Participants

3

Reactant 2

HCID 12052TriethylsilaneHCID 22660526HCID 22660526, compound

Product 1

HCID 15429138HCID 15429138, compound

Conditions

Temperature
60 °C

Procedure

A 50 ml reaction flask was charged with 11.6 ml (100 mmol) of 1,4-butandiol-mono vinylether and a catalytic amount of divinyl-tetramethyl disiloxane platinum complex under inert atmosphere and heated to 60° C. 10.4 g (90 mmol) of triethylsilane was slowly added to the reaction flask through a dropping funnel. The exothermic reaction mixture was stirred at 75° C. for 18 hours, followed by distillation at 105° C. to 107° C./0.2 mbar over a 10 cm Vigreux column. This reaction yielded 15.2 g (66% of the theory) of a clear liquid. Purity according to gas chromatography was 98.7%.

Workup

  1. customA 50 ml reaction flask
  2. distillationfollowed by distillation at 105° C. to 107° C./0.2 mbar over a 10 cm Vigreux column
  3. customThis reaction yielded 15.2 g (66% of the theory) of a clear liquid

Sources & evidence

ORD record
ord-f8cd59f4bf15483e8ef816b0ad188406
Source dataset
uspto-grants-2002_07
Patent number
US06416746B1

Reaction notes

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