Triethylamine → HCID 18468886, compound

HRID 2229748Notes

Reaction equation

HRID 2229748 reaction equation
Cl[Si:2]([CH3:17])([CH3:16])[CH:3]1[C:14]2[C:6](=[CH:7][C:8]3[CH2:9][CH2:10][CH2:11][C:12]=3[CH:13]=2)[CH:5]=[C:4]1[CH3:15].CCN(CC)CC.C[SiH]([N:28](C1C2C(=C(C)C=C(C)C=2)C(C)=C1C)[CH:29]1[CH2:34][CH2:33][CH2:32][CH2:31][CH2:30]1)C>CCCCCC>[CH:29]1([NH:28][Si:2]([CH3:17])([CH3:16])[CH:3]2[C:14]3[C:6](=[CH:7][C:8]4[CH2:9][CH2:10][CH2:11][C:12]=4[CH:13]=3)[CH:5]=[C:4]2[CH3:15])[CH2:34][CH2:33][CH2:32][CH2:31][CH2:30]1

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 18468888HCID 18468888, compoundHCID 131723404HCID 131723404, compound

Product 1

HCID 18468886HCID 18468886, compoundYield 94.3%

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Chlorodimethyl(1,5,6,7-tetrahydro-2-methyl-s-indacen-1-yl) silane (5.67 g, 0.0216 moles) was stirred in hexane (50 mL) as NEt3 (2.18 g, 0.0216 moles) and cyclohexylamine (2.13 g, 0.0216 moles) were added. This mixture was allowed to stir 16 hours. After the reaction period the mixture was filtered and the volatiles removed resulting in the isolation of the desired product as a yellow oil (6.62 g, 94.3 percent).

Workup

  1. additionwere added
  2. customAfter the reaction period the mixture
  3. filtrationwas filtered
  4. customthe volatiles removed

Sources & evidence

ORD record
ord-9157eb99d6844ed89c243fd6e0f43e4f
Source dataset
uspto-grants-2002_07
Patent number
US06420507B1

Reaction notes

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