Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Butyl vinyl ether | HCID 8108 | — |
| Reactant | Benzene, 1-bromo-3-(trifluoromethyl)- | HCID 9817 | — |
| Reactant | Hexadecane | HCID 11006 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Solvent | Propylene Carbonate | HCID 7924 | — |
| Product | HCID 18469473 | HCID 18469473 | — |
Reaction Steps
26 mg (0.025 mmol) bis-(dibenzalacetone)-chloroform-palladium and different amounts of triphenyl phosphine are placed in a Schlenk-tube under argon. 4 ml propylene carbonate, 1.12 g (5 mmol) 3-bromo-benzotrifluoride 0.76 g (7.5 mmol) triethyl amine and 0.75 g (7.5 mmol) butyl vinyl ether are added. The reaction mixture is heated to 120° C. for 20 hours. It is cooled to room temperature and 200 mg hexadecane (internal standard) and 15 ml diethyl ether are added. The mixture is analysed by GC.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06420608B1 |
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| Source dataset | uspto-grants-2002_07 |
|---|
| ORD ID | ord-ed67e109ff974e1590c43a2215caa79d |
|---|
| Source note | uspto-grants-2002_07 |
|---|
