Butyl vinyl ether → HCID 18469473, compound

HRID 2229890Notes

Reaction equation

[C:1]1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=C[CH:2]=1.Br[C:21]1[CH:22]=[C:23]([C:27]([F:30])([F:29])[F:28])[CH:24]=[CH:25][CH:26]=1.C([O:33][CH2:34][CH2:35][CH2:36][CH3:37])=C.CCCCCCCCCCCCCCCC>C(OCC)C.C1(=O)OC(C)CO1>[F:28][C:27]([F:30])([F:29])[C:23]1[CH2:22][C:21]([O:33][CH2:34][CH2:35][CH2:36][CH3:37])([CH:26]=[CH:25][CH:24]=1)[CH:1]=[CH2:2]

Participants

Conditions

Temperature: 120 °C

Procedure

26 mg (0.025 mmol) bis-(dibenzalacetone)-chloroform-palladium and different amounts of triphenyl phosphine are placed in a Schlenk-tube under argon. 4 ml propylene carbonate, 1.12 g (5 mmol) 3-bromo-benzotrifluoride 0.76 g (7.5 mmol) triethyl amine and 0.75 g (7.5 mmol) butyl vinyl ether are added. The reaction mixture is heated to 120° C. for 20 hours. It is cooled to room temperature and 200 mg hexadecane (internal standard) and 15 ml diethyl ether are added. The mixture is analysed by GC.

Workup

temperatureIt is cooled to room temperature

Sources & evidence

ORD record: ord-ed67e109ff974e1590c43a2215caa79d
Source dataset: uspto-grants-2002_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06420608B1

Reaction notes

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