2,2-Dimethyl-1,3-dioxane-4,6-dione → Ethyl 3-oxoheptanoate

HRID 2233880Notes

Reaction equation

[C:1](Cl)(=O)[CH2:2][CH2:3][CH2:4]C.C[C:9]1([CH3:17])[O:14][C:13](=[O:15])[CH2:12][C:11](=[O:16])O1>>[O:16]=[C:11]([CH2:1][CH2:2][CH2:3][CH3:4])[CH2:12][C:13]([O:14][CH2:9][CH3:17])=[O:15]

Participants

Reactant 2

HCID 162492,2-Dimethyl-1,3-dioxane-4,6-dione

HCID 61186Valeryl chloride

Product 1

HCID 559036Ethyl 3-oxoheptanoate

Procedure

The title compound was prepared in a manner analogous to Intermediate 123 from valeryl chloride and 2,2-dimethyl-1,3-dioxane-4,6-dione (both commercially available).

Sources & evidence

ORD record: ord-00f1992cc1c445ecb211852576c2a09f
Source dataset: uspto-grants-2010_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07709503B2

Reaction notes

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