Allylamine → HCID 54039229, compound

HRID 223638Notes

Reaction equation

HRID 223638 reaction equation
[O:1]1[CH:5]=[CH:4][CH2:3][C:2]1=[CH:6][CH:7]=[CH:8]N.[CH2:10]([NH2:13])[CH:11]=[CH2:12]>>[CH3:12][CH:11]1[CH2:7][CH:6]=[CH:2][CH2:3][CH2:4][CH:5]=[CH:8][CH2:7][CH:6]([C:2]2[O:1][CH:5]=[CH:4][CH:3]=2)[N:13]=[CH:10]1

Participants

3

Reactant 2

HCID 7853AllylamineHCID 86737848HCID 86737848, compound

Product 1

HCID 54039229HCID 54039229, compound

Procedure

The procedure described in Example 1(a) is repeated, except that 273 g (2.02 mols) of N-2-furylidenepropenylamine [prepared by reaction of 2-furylaldehyde with allylamine and subsequent isomerisation in the presence of potassium tert.-butylate; boiling point 60°-62° C./67 Pa; nD20 =1.6004] are used. Distillation yields 210 g (0.865 mol) of 3-methyl-12-(2-furyl)-1-aza-1,5,9-cyclododecatriene; boiling point 106°-108° C./4 Pa; nD20 =1.5260.

Workup

  1. distillationDistillation

Sources & evidence

ORD record
ord-57acaa84ecf747e1b3f83df400ddb8ba
Source dataset
uspto-grants-1982_10
Patent number
US04355177

Reaction notes

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