Hydrochloric Acid → HCID 73678918, compound

HRID 223641Notes

Reaction equation

HRID 223641 reaction equation
[CH3:1][C:2]1([CH3:20])[CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[N:4]=[CH:3]1.S(O)(O)(=O)=O.[NH2:26][OH:27].Cl>O>[CH3:1][C:2]([CH3:20])([CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[NH2:4])[CH:3]=[N:26][OH:27]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 159255Hydroxylamine, sulfate (1:1)HCID 54113944HCID 54113944, compound

Product 1

HCID 73678918HCID 73678918, compoundYield 200.5%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The procedure described in Example 1(b) is repeated, except that 113 g (0.41 mol) of 3,3-dimethyl-12-hexyl-1-aza-1,5,9-cyclododecatriene, 33 g (0.202 mol) of hydroxylamine sulfate, 50 g of concentrated hydrochloric acid and 250 ml of water are used. Working up yields 125 g (0.405 mol) of 2,2-dimethyl-11-n-hexyl-11-amino-undeca-4,8-dienal oxime; yield 99% of theory.

Sources & evidence

ORD record
ord-e81fac2e9153415ca25fe5683600464e
Source dataset
uspto-grants-1982_10
Patent number
US04355177

Reaction notes

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