Hydrochloric Acid → HCID 73678921, compound

HRID 223647Notes

Reaction equation

HRID 223647 reaction equation
[CH3:1][CH:2]1[CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH:16]=[CH:17][CH3:18])[CH3:15])[N:4]=[CH:3]1.S(O)(O)(=O)=O.[NH2:24][OH:25].Cl>O>[CH3:1][CH:2]([CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH:16]=[CH:17][CH3:18])[CH3:15])[NH2:4])[CH:3]=[N:24][OH:25]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 159255Hydroxylamine, sulfate (1:1)HCID 54073519HCID 54073519, compound

Product 1

HCID 73678921HCID 73678921, compoundYield 195.2%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The procedure described in Example 1(b) is repeated, except that 122.7 g (0.5 mol) of 3-methyl-12-(3-penten-2-yl)-1-aza-1,5,9-cyclododecatriene, 41.1 g (0.25 mol) of hydroxylamine sulfate, 50 ml of concentrated hydrochloric acid and 250 ml of water are used. Working up yields 135.9 g (0.488 mol) of 2-methyl-11-(3-penten-2-yl)-11-amino-undeca-4,8-dienal oxime; yield 97.6% of theory. nD20 =1.5091.

Sources & evidence

ORD record
ord-507848ef97c64c03b08d2f964a918db0
Source dataset
uspto-grants-1982_10
Patent number
US04355177

Reaction notes

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