Hydrazine hydrate (1:1) → HCID 67363473, compound

HRID 2243911Notes

Reaction equation

HRID 2243911 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[CH:27]=[CH:26][C:25]([F:28])=[CH:24][C:23]=1[Cl:29])=O)(=O)OC.O.[NH2:31][NH2:32]>>[Cl:29][C:23]1[CH:24]=[C:25]([F:28])[CH:26]=[CH:27][C:22]=1[C:20]1[CH:19]=[C:4]2[C:3]([C@:2]3([CH3:1])[C:8]([CH3:10])([CH3:9])[C@H:5]2[CH2:6][CH2:7]3)=[N:32][N:31]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609916HCID 86609916, compound

Product 1

HCID 67363473HCID 67363473, compound

Procedure

yellow solid. MS (EI): 316.0 (M+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo [2.2.1]heptane-2,3-dione, [2-(2-Chloro-4-fluoro-phenyl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-c77a9d34e33c4205ab32b441af6cb310
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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