Hydrazine hydrate (1:1) → HCID 67363391, compound

HRID 2243914Notes

Reaction equation

HRID 2243914 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[CH:27]=[C:26]([O:28][CH3:29])[C:25]([F:30])=[CH:24][C:23]=1[Cl:31])=O)(=O)OC.O.[NH2:33][NH2:34]>>[Cl:31][C:23]1[CH:24]=[C:25]([F:30])[C:26]([O:28][CH3:29])=[CH:27][C:22]=1[C:20]1[CH:19]=[C:4]2[C:3]([C@:2]3([CH3:1])[C:8]([CH3:10])([CH3:9])[C@H:5]2[CH2:6][CH2:7]3)=[N:34][N:33]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609917HCID 86609917, compound

Product 1

HCID 67363391HCID 67363391, compound

Procedure

yellow solid. MS (EI): 347.1 (M+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, [2-(2-Chloro-4-fluoro-5-methoxy-phenyl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-6d28bc7a447f499194da0596d42deb1e
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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