Hydrazine hydrate (1:1) → HCID 67364483, compound

HRID 2243922Notes

Reaction equation

HRID 2243922 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[S:26][C:25]([C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)=[N:24][C:23]=1[CH3:33])=O)(=O)OC.O.[NH2:35][NH2:36]>>[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4]1[C:3]2=[N:35][N:36]=[C:20]([C:22]2[S:26][C:25]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=3)=[N:24][C:23]=2[CH3:33])[CH:19]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609921HCID 86609921, compound

Product 1

HCID 67364483HCID 67364483, compound

Procedure

orange solid. MS (EI): 361.0 (M+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, [2-(4-Methyl-2-phenyl-thiazol-5-yl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-e923dbe030c445aa918adc82f5b07146
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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