HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrazine hydrate (1:1) → (1S,8R)-5-(4-Chloro-2-methyl-phenyl)-1,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Reactant | (+)-Camphorquinone | HCID 1549179 | — |
| Reactant | [2-(4-Chloro-2-methyl-phenyl)-2-oxo-ethyl]-phosphonic acid dimethyl ester | HCID 86609922 | — |
| Product | (1S,8R)-5-(4-Chloro-2-methyl-phenyl)-1,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2(7),3,5-triene | HCID 67364461 | — |
Reaction Steps
yellow solid. MS (EI): 312.2 (M+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo [2.2.1]heptane-2,3-dione, [2-(4-Chloro-2-methyl-phenyl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07678795B2 |
| Source dataset | uspto-grants-2010_03 |
| ORD ID | ord-dc669a11d9884a819f51e38febee58c2 |
| Source note | uspto-grants-2010_03 |