Hydrazine hydrate (1:1) → HCID 67364260, compound

HRID 2243950Notes

Reaction equation

HRID 2243950 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1([CH3:25])[CH2:24][CH2:23]1)=O)(=O)OC.O.[NH2:27][NH2:28]>>[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4]1[C:3]2=[N:27][N:28]=[C:20]([C:22]2([CH3:25])[CH2:24][CH2:23]2)[CH:19]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609924HCID 86609924, compound

Product 1

HCID 67364260HCID 67364260, compound

Procedure

light yellow oil. MS (ESI): 243.2 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo [2.2.1]heptane-2,3-dione, [2-(1-Methyl-cyclopropyl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-7ce1f7d1ad0e42a58e902412fa438dda
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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