Hydrazine hydrate (1:1) → HCID 67364595, compound

HRID 2243952Notes

Reaction equation

[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[CH:23]=[N:24][N:25]([C:28]([CH3:31])([CH3:30])[CH3:29])[C:26]=1[CH3:27])=O)(=O)OC.O.[NH2:33][NH2:34]>>[C:28]([N:25]1[C:26]([CH3:27])=[C:22]([C:20]2[CH:19]=[C:4]3[C:3]([C@:2]4([CH3:1])[C:8]([CH3:10])([CH3:9])[C@H:5]3[CH2:6][CH2:7]4)=[N:34][N:33]=2)[CH:23]=[N:24]1)([CH3:31])([CH3:30])[CH3:29]

Participants

Reactant 3

HCID 24654Hydrazine hydrate (1:1)

HCID 1549179(+)-Camphorquinone

HCID 86609929HCID 86609929, compound

Product 1

HCID 67364595HCID 67364595, compound

Procedure

yellow crystalline solid. MS (ESI): 325.2 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo [2.2.1]heptane-2,3-dione, [2-(1-tert-Butyl-5-methyl-1H-pyrazol-4-yl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record: ord-83851dbe5d4c49198a8f2c678961d1d8
Source dataset: uspto-grants-2010_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07678795B2

Reaction notes

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