Hydrazine hydrate (1:1) → HCID 67364466, compound

HRID 2243959Notes

Reaction equation

HRID 2243959 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[CH:23]=[N:24][N:25]([CH3:30])[C:26]=1[CH:27]1[CH2:29][CH2:28]1)=O)(=O)OC.O.[NH2:32][NH2:33]>>[CH:27]1([C:26]2[N:25]([CH3:30])[N:24]=[CH:23][C:22]=2[C:20]2[CH:19]=[C:4]3[C:3]([C@:2]4([CH3:1])[C:8]([CH3:10])([CH3:9])[C@H:5]3[CH2:6][CH2:7]4)=[N:33][N:32]=2)[CH2:29][CH2:28]1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609931HCID 86609931, compound

Product 1

HCID 67364466HCID 67364466, compound

Procedure

yellow foam. MS (ESI): 309.1 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, [2-(5-Cyclopropyl-1-methyl-1H-pyrazol-4-yl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-cbd19bacbb864732babf7d36707c7027
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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