Hydrazine hydrate (1:1) → HCID 67363669, compound

HRID 2243965Notes

Reaction equation

HRID 2243965 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[C:23]([CH3:28])=[N:24][N:25]([CH3:27])[CH:26]=1)=O)(=O)OC.O.[NH2:30][NH2:31]>>[CH3:27][N:25]1[CH:26]=[C:22]([C:20]2[CH:19]=[C:4]3[C:3]([C@:2]4([CH3:1])[C:8]([CH3:10])([CH3:9])[C@H:5]3[CH2:6][CH2:7]4)=[N:31][N:30]=2)[C:23]([CH3:28])=[N:24]1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609932HCID 86609932, compound

Product 1

HCID 67363669HCID 67363669, compound

Procedure

yellow solid. MS (EI): 282.3 (M+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, [2-(1,3-Dimethyl-1H-pyrazol-4-yl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-8acd31f6a6484a4a93f2b956b1dc3c6d
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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