Hydrazine hydrate (1:1) → HCID 67367057, compound

HRID 2243967Notes

Reaction equation

HRID 2243967 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[CH:23]=[N:24][N:25]([CH2:31][C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[C:26]=1[C:27]([F:30])([F:29])[F:28])=O)(=O)OC.O.[NH2:39][NH2:40]>>[CH2:31]([N:25]1[C:26]([C:27]([F:30])([F:29])[F:28])=[C:22]([C:20]2[CH:19]=[C:4]3[C:3]([C@:2]4([CH3:1])[C:8]([CH3:10])([CH3:9])[C@H:5]3[CH2:6][CH2:7]4)=[N:40][N:39]=2)[CH:23]=[N:24]1)[C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609934HCID 86609934, compound

Product 1

HCID 67367057HCID 67367057, compound

Procedure

yellow oil. MS (EI): 413.2 (M+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, [2-(1-Benzyl-5-trifluoromethyl-1H-pyrazol-4-yl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-fb3c0826f4844d978f06c9664605808f
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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