Hydrazine hydrate (1:1) → HCID 67364974, compound

HRID 2243968Notes

Reaction equation

HRID 2243968 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[CH:23]=[N:24][N:25]([CH2:28][C:29]2[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=2)[C:26]=1[CH3:27])=O)(=O)OC.O.[NH2:36][NH2:37]>>[CH2:28]([N:25]1[C:26]([CH3:27])=[C:22]([C:20]2[CH:19]=[C:4]3[C:3]([C@:2]4([CH3:1])[C:8]([CH3:10])([CH3:9])[C@H:5]3[CH2:6][CH2:7]4)=[N:37][N:36]=2)[CH:23]=[N:24]1)[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609935HCID 86609935, compound

Product 1

HCID 67364974HCID 67364974, compound

Procedure

light brown amorphous solid. MS (ESI): 359.1 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, [2-(1-Benzyl-5-methyl-1H-pyrazol-4-yl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-12a354190d0a480086a07b97f00940fb
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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