Hydrazine hydrate (1:1) → HCID 67364726, compound

HRID 2243972Notes

Reaction equation

[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20]([C:22]1[CH:23]=[N:24][N:25]([C:33]([CH3:36])([CH3:35])[CH3:34])[C:26]=1[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1)=O)(=O)OC.O.[NH2:38][NH2:39]>>[C:33]([N:25]1[C:26]([C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)=[C:22]([C:20]2[CH:19]=[C:4]3[C:3]([C@:2]4([CH3:1])[C:8]([CH3:10])([CH3:9])[C@H:5]3[CH2:6][CH2:7]4)=[N:39][N:38]=2)[CH:23]=[N:24]1)([CH3:36])([CH3:35])[CH3:34]

Participants

Reactant 3

HCID 24654Hydrazine hydrate (1:1)

HCID 1549179(+)-Camphorquinone

HCID 86609937HCID 86609937, compound

Product 1

HCID 67364726HCID 67364726, compound

Procedure

light yellow solid. MS (EI): 386.3 (M+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo [2.2.1]heptane-2,3-dione, [2-(1-tert-Butyl-5-phenyl-1H-pyrazol-4-yl)-2-oxo-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record: ord-c3873da685ea459393115bc6fb429ea7
Source dataset: uspto-grants-2010_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07678795B2

Reaction notes

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