Hydrazine hydrate (1:1) → HCID 67363727, compound

HRID 2243974Notes

Reaction equation

HRID 2243974 reaction equation
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20](=O)[C:21]1([C:24]([F:27])([F:26])[F:25])[CH2:23][CH2:22]1)(=O)OC.O.[NH2:30][NH2:31]>>[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4]1[C:3]2=[N:30][N:31]=[C:20]([C:21]2([C:24]([F:27])([F:26])[F:25])[CH2:23][CH2:22]2)[CH:19]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 1549179(+)-CamphorquinoneHCID 86609938HCID 86609938, compound

Product 1

HCID 67363727HCID 67363727, compound

Procedure

yellow solid. MS (ESI): 297.1 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, [[2-Oxo-2-(1-trifluoromethyl-cyclopropyl)-ethyl]-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-0df786608bb54bca8322e51ddc63035f
Source dataset
uspto-grants-2010_03
Patent number
US07678795B2

Reaction notes

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