Imidazole → HCID 20442094, compound

HRID 224559Notes

Reaction equation

HRID 224559 reaction equation
[CH2:1]([Sn:5]([CH2:20][CH2:21][CH2:22][CH3:23])([CH2:16][CH2:17][CH2:18][CH3:19])/[CH:6]=[CH:7]/[C:8]([CH3:15])([OH:14])[CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:2][CH2:3][CH3:4].N1C=CN=C1.Cl[Si:30]([CH3:33])([CH3:32])[CH3:31]>CN(C)C=O>[CH2:20]([Sn:5]([CH2:16][CH2:17][CH2:18][CH3:19])([CH2:1][CH2:2][CH2:3][CH3:4])/[CH:6]=[CH:7]/[C:8]([CH3:15])([O:14][Si:30]([CH3:33])([CH3:32])[CH3:31])[CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:21][CH2:22][CH3:23]

Participants

5

Reactant 3

HCID 795ImidazoleHCID 6397ChlorotrimethylsilaneHCID 20442092HCID 20442092, compound

Product 1

HCID 20442094HCID 20442094, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

The vinylstannane is treated with imidazole, and chlorotrimethylsilane in dimethylformamide by the procedure of Example 1 to provide (E)-1-tri-n-butylstannyl-3-methyl-3-trimethylsilyloxy-1-octene as an oil.

Sources & evidence

ORD record
ord-3007942d440d464a8d4db300f06bc5d4
Source dataset
uspto-grants-1980_11
Patent number
US04233231

Reaction notes

Loading…