Diisopropylaniline → HCID 68550176, compound

HRID 2245627Notes

Reaction equation

[CH:1]([C:4]1[CH:10]=[CH:9][CH:8]=[C:7]([CH:11]([CH3:13])[CH3:12])[C:5]=1[NH2:6])([CH3:3])[CH3:2].[CH2:14]1[C:27]2[C:18](=[N:19][C:20]3[C:21](=O)[CH2:22][CH2:23][CH2:24][C:25]=3[CH:26]=2)[C:17](=O)[CH2:16][CH2:15]1>>[CH:11]([C:7]1[CH:8]=[CH:9][CH:10]=[C:4]([CH:1]([CH3:3])[CH3:2])[C:5]=1[N:6]=[C:17]1[C:18]2[C:27](=[CH:26][C:25]3[CH2:24][CH2:23][CH2:22][C:21](=[N:6][C:5]4[C:7]([CH:11]([CH3:12])[CH3:13])=[CH:8][CH:9]=[CH:10][C:4]=4[CH:1]([CH3:3])[CH3:2])[C:20]=3[N:19]=2)[CH2:14][CH2:15][CH2:16]1)([CH3:13])[CH3:12]

Participants

Reactant 2

HCID 32484Diisopropylaniline

HCID 355603HCID 355603, compound

Product 1

HCID 68550176HCID 68550176, compound

Procedure

was synthesized by methods similar to those in Examples 3 and 4:: 2,6-di-iso-propylaniline was condensed with 2,3,7,8-tetrahydro-1H,6H-acridine-4,5-dione to yield 4,5-bis[2,6-di-iso-propylphenylimino]-1,2,3,4,5,6,7,8-octahydroacridine (4). The complexation of (4) with FeCl2.4H2O was carried out with azeotropic removal of methanol in benzene. The structure of the final complex was proved by direct probe GC. Exact mass direct probe calculated for C37H47Cl2FeN3: 659.25. Found: 659.25.

Workup

customwas synthesized by methods similar to those in Examples 3 and 4

Sources & evidence

ORD record: ord-1069ed338a5341aca9f73d7ba24a7945
Source dataset: uspto-grants-2010_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07683149B2

Reaction notes

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