Diethyl Ether → Silver isobutyrylacetate

HRID 2245811Notes

Reaction equation

HRID 2245811 reaction equation
N(CCO)CCO.CCOCC.[C:13]([CH2:18][C:19]([OH:21])=[O:20])(=[O:17])[CH:14]([CH3:16])[CH3:15].[N+]([O-])([O-])=O.[Ag+:26]>O>[C:13]([CH2:18][C:19]([O-:21])=[O:20])(=[O:17])[CH:14]([CH3:16])[CH3:15].[Ag+:26]

Participants

6

Reactant 4

HCID 3283Diethyl EtherHCID 8113DiethanolamineHCID 24470Silver NitrateHCID 4400244-Methyl-3-oxopentanoic acid

Product 1

HCID 86633510Silver isobutyrylacetateYield 52%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Diethanolamine (0.33 g) was dissolved in water (5 mL), and to this was added an ether solution (10 mL) containing isobutyrylacetic acid (0.43 g). Next, the mixture was stirred at 15° C. while an aqueous solution (5 mL) containing silver nitrate (0.51 g) was added dropwise, and this further was stirred for 15 minutes. The white precipitate that settled was filtered off to obtain silver isobutyrylacetate (yield 0.37 g). FIG. 1 shows the infrared absorption spectrum (IR) of the silver isobutyrylacetate that was obtained. IR:1709 cm−1, 1505 cm−1.

Workup

  1. additionwas added dropwise
  2. filtrationThe white precipitate that settled was filtered off

Sources & evidence

ORD record
ord-a1e81e788fd240a3af4fc58360d5f276
Source dataset
uspto-grants-2010_03
Patent number
US07683195B2

Reaction notes

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