HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2246532Generated: October 31, 2026
Potassium ethanethioate → HCID 74437522, compound
https://huagongshe.com/reaction/2246532
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Potassium ethanethioate | HCID 23670855 | — |
| Reactant | 11-(4S)-[2-(chloromethyldimethylsilanyl)-ethyl]-4-ethyl-4-hydroxy-1,12-dihydro-4H-2-oxa-6,12a-diaza-dibenzo[b,h]fluorene-3,13-dione | HCID 25227497 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 74437522 | HCID 74437522 | 74% |
Reaction Steps
A mixture of Compound 3 (300 mg) and potassium thioacetate (400 mg) in N,N-dimethylformamide (2 mL) was heated at 70° C. under argon for 16 hours. The N,N-dimethylformamide was removed under vacuum and the resulting residue was directly eluted on a silica gel using 1% ethanol in dichloromethane to obtain the required product in 74% yield (240 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07687496B2 |
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| Source dataset | uspto-grants-2010_03 |
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| ORD ID | ord-3dc512f6fb724db99a5530ed5c83df75 |
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| Source note | uspto-grants-2010_03 |
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