5-Hexyl-2-phenoxyphenol → 5-Octyl-2-phenoxyphenol

HRID 2246762Notes

Reaction equation

HRID 2246762 reaction equation
C(C1C=CC(OC2C=CC=CC=2)=C(O)C=1)CCCCC.C(C1C=CC(OC2C=CC=CC=2)=C(OC)C=1)CCCCC.C[O:43][C:44]1[CH:49]=[C:48]([CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH3:57])[CH:47]=[CH:46][C:45]=1[O:58][C:59]1[CH:64]=[CH:63][CH:62]=[CH:61][CH:60]=1>>[CH2:50]([C:48]1[CH:47]=[CH:46][C:45]([O:58][C:59]2[CH:64]=[CH:63][CH:62]=[CH:61][CH:60]=2)=[C:44]([OH:43])[CH:49]=1)[CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH3:57]

Participants

4

Reactant 3

HCID 52749775-Hexyl-2-phenoxyphenolHCID 684236592-Methoxy-4-octyl-1-phenoxybenzeneHCID 684255854-Hexyl-2-methoxy-1-phenoxybenzene

Product 1

HCID 52749795-Octyl-2-phenoxyphenol

Procedure

The procedure as described above for synthesis of (5a) was used, except that compound (4a) was replaced with compound (4b). 1H NMR (300 MHz) (CDCl3) δ 7.43-6.72 (m, 8H), 5.58 (s, 1H), 2.66-2.61 (t, 2H), 1.71-1.66 (m, 2H), 1.39-1.35 (m, 10H), 0.99-0.95 (t, 3H).

Sources & evidence

ORD record
ord-4396f75bce7949e8aeaae66ff71e9609
Source dataset
uspto-grants-2010_03
Patent number
US07687547B2

Reaction notes

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