1,12-Dodecanediamine → HCID 18644958, compound

HRID 2248067Notes

Reaction equation

[CH2:1]([OH:23])[C@H:2]1[O:7][C@@H:6]([O:8][C@H:9]2[C@H:15]([OH:16])[C@@H:14]([OH:17])[C:12](=[O:13])[O:11][C@@H:10]2[CH2:18][OH:19])[C@H:5]([OH:20])[C@@H:4]([OH:21])[C@@H:3]1[OH:22].[NH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][NH2:37]>>[CH2:36]([NH:37][C:12]([C@@H:14]([C@H:15]([C@@H:9]([C@@H:10]([CH2:18][OH:19])[OH:11])[O:8][C@@H:6]1[O:7][C@H:2]([CH2:1][OH:23])[C@@H:3]([OH:22])[C@H:4]([OH:21])[C@H:5]1[OH:20])[OH:16])[OH:17])=[O:13])[CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][NH:24][C:12]([C@@H:14]([C@H:15]([C@@H:9]([C@@H:10]([CH2:18][OH:19])[OH:11])[O:8][C@@H:6]1[O:7][C@H:2]([CH2:1][OH:23])[C@@H:3]([OH:22])[C@H:4]([OH:21])[C@H:5]1[OH:20])[OH:16])[OH:17])=[O:13]

Participants

Reactant 2

HCID 177271,12-Dodecanediamine

HCID 99211Cellobionolactone

Product 1

HCID 18644958HCID 18644958, compoundYield 22.7%

Procedure

2.04 g of cellobiono-1,5-lactone (H. W. Diehl et al., Carbohydr. Res. 38, 364 (1974)) are reacted with 0.60 g of 1,12-diaminododecane analogously to Example 5 and 0.60 g of the title compound are obtained.

Sources & evidence

ORD record: ord-b2b9455041724a04ba4317a98ce4122b
Source dataset: uspto-grants-1991_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05037973

Reaction notes

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