HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acetate → HCID 67808707, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | 6-(Pyridin-3-YL)hex-5-YN-1-OL | HCID 13557551 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 67808707 | HCID 67808707 | 46% |
Reaction Steps
6-(3-Pyridyl)-1-hex-5-ynol (0.15 g, 0.86 mmol) was added to a stirred suspension of 10% palladium on charcoal (20 mg) in ethanol. The reaction was stirred at room temperature under hydrogen for 24 h. The mixture was filtered through celite and evaporated to give a clear oil. Column chromatography (flash silica gel; ethyl acetate) gave Z-6-(3-pyridyl)-1-hex-5-enol (70 mg, 46%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05428168 |
| Source dataset | uspto-grants-1995_06 |
| ORD ID | ord-14b42dda1a0a43b6a9e6712d1e2c1bcf |
| Source note | uspto-grants-1995_06 |