Methylamine → HCID 19810333, compound

HRID 2248838Notes

Reaction equation

HRID 2248838 reaction equation
[C:1]1([Al:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:20][NH2:21]>C1(C)C=CC=CC=1>[C:14]1([Al:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1.[CH3:20][NH2:21]

Participants

4

Reactant 2

HCID 6329MethylamineHCID 16684219Aluminum, triphenyl-

Product 1

HCID 19810333HCID 19810333, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Laubengayer et al., Inorg. Chem., 1, pages 632 to 637 (1962), disclose the reaction of triphenylaluminum and methylamine in toluene solution to form methylamine triphenylaluminum, then methylaminodiphenylaluminum, and then methyliminophenylaluminum. Triphenylaluminum and dimethylamine form dimethylamine triphenylaluminum which is heated to form dimethylaminodiphenylaluminum.

Sources & evidence

ORD record
ord-a6a5179c1d334cff9912791b76342f7c
Source dataset
uspto-grants-1991_08
Patent number
US05041512

Reaction notes

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