HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanesulfonyl chloride → HCID 19019875, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanesulfonyl chloride | HCID 31297 | — |
| Reactant | 3-(1-Azidotridecyl)-2-triethylsilylfuran | HCID 19019887 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Product | HCID 19019875 | HCID 19019875 | — |
Reaction Steps
Reducing 3-(1-azidotridecyl)-2-triethylsilylfuran (Compound 24 with lithium aluminum hydride, as in Example 8, followed by reacting the intermediate with methanesulfonyl chloride, gives 3-(1-methanesulfonamidotridecyl)-2-triethylsilylfuran (Compound 26). Oxidizing this sulfonamide, under conditions as in Example 1, followed by reduction with sodium borohydride gives 3-(1-methanesulfonamidotridecyl)-2(5H)-furanone (Compound 11).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05043457 |
| Source dataset | uspto-grants-1991_08 |
| ORD ID | ord-59d114cdef2b4d8db45242616d19f1a6 |
| Source note | uspto-grants-1991_08 |