Methyldichlorosilane → HCID 123155376, compound

Participants

Reaction Steps

After a reactor of 150 mL stainless steel tube was cooled under the dried nitrogen condition, 26.37 g (0.199 mol) of dicyclopentadiene, 34.34 g (0.299 mol) of methyldichlorosilane, 0.036 g (0.000203 mol) of palladium dichloride, 100 μL (0,000406 mol) of tributylphosphine and 30 mL of toluene and 10 mL of hexadecane were placed in a reactor. The reactor was sealed and the reaction was performed at 180° C. for 1 hour. Products were subject to simple vacuum distillation, thereby providing a mixture (98.3 g) of (2-cyclopentenyl)methyldichlorosilane (43.3 g, 80%), other unreacted reactants, toluene, hexadecane, and unidentified compounds.

Provenance & Evidence