Methyldichlorosilane → HCID 123155376, compound

HRID 2249927Notes

Reaction equation

HRID 2249927 reaction equation
[CH2:1]1[CH:5]2[CH:6]3C=CC([CH:4]2[CH:3]=[CH:2]1)C3.C[SiH:12]([Cl:14])[Cl:13].CCCCCCCCCCCCCCCC>[Pd](Cl)Cl.C(P(CCCC)CCCC)CCC.C1(C)C=CC=CC=1>[CH:5]1([CH2:6][SiH:12]([Cl:14])[Cl:13])[CH2:4][CH2:3][CH:2]=[CH:1]1

Participants

7

Reactant 3

HCID 6376MethyldichlorosilaneHCID 6492DicyclopentadieneHCID 11006Hexadecane

Product 1

HCID 123155376HCID 123155376, compoundYield 272.7%

Reagents, catalysts & solvents 3

HCID 13831TributylphosphineCatalystHCID 24290Palladium ChlorideCatalystHCID 1140TolueneSolvent

Procedure

After a reactor of 150 mL stainless steel tube was cooled under the dried nitrogen condition, 26.37 g (0.199 mol) of dicyclopentadiene, 34.34 g (0.299 mol) of methyldichlorosilane, 0.036 g (0.000203 mol) of palladium dichloride, 100 μL (0,000406 mol) of tributylphosphine and 30 mL of toluene and 10 mL of hexadecane were placed in a reactor. The reactor was sealed and the reaction was performed at 180° C. for 1 hour. Products were subject to simple vacuum distillation, thereby providing a mixture (98.3 g) of (2-cyclopentenyl)methyldichlorosilane (43.3 g, 80%), other unreacted reactants, toluene, hexadecane, and unidentified compounds.

Workup

  1. customwere placed in a reactor
  2. customThe reactor was sealed
  3. distillationProducts were subject to simple vacuum distillation

Sources & evidence

ORD record
ord-58ac2a2873fb43aaa3c49bd9f93a740c
Source dataset
uspto-grants-2008_01
Patent number
US07314946B2

Reaction notes

Loading…