HCID 59643063, compound → HCID 59643052, compound

HRID 2251612Notes

Reaction equation

HRID 2251612 reaction equation
[C:1]([C:4]1[CH:9]=[CH:8][C:7]([O:10][CH2:11][O:12][CH3:13])=[C:6]([O:14][CH3:15])[CH:5]=1)([CH3:3])=[CH2:2]>CO.[Pd]>[CH:1]([C:4]1[CH:9]=[CH:8][C:7]([O:10][CH2:11][O:12][CH3:13])=[C:6]([O:14][CH3:15])[CH:5]=1)([CH3:3])[CH3:2]

Participants

4

Reactant 1

HCID 59643063HCID 59643063, compound

Product 1

HCID 59643052HCID 59643052, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

To a solution of 4-isopropenyl-2-methoxy-1-methoxymethoxy-benzene (3.5 g, 16.81 mmol) in 20 mL MeOH, Pd/C (10%, 350 mg) was added and the mixture was stirred 16 h under a H2 atmosphere. The reaction mixture was then filtered through Celite and evaporated in vacuo and briefly dried under vacuum to yield the title compound as a colorless oil.

Workup

  1. filtrationThe reaction mixture was then filtered through Celite
  2. customevaporated in vacuo
  3. custombriefly dried under vacuum

Sources & evidence

ORD record
ord-9268edd1e713488bb67119630f1e5147
Source dataset
uspto-grants-2008_01
Patent number
US07319101B2

Reaction notes

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