Sodium periodate → HCID 23329598, compound

HRID 225212Notes

Reaction equation

HRID 225212 reaction equation
[CH3:1][C:2]1[CH:15]=[CH:14][C:13]2[C@@H:12]3[CH:16]([OH:19])[CH:17]([OH:18])[C@@H:5]([C:6]4[C:11]3=[CH:10][CH:9]=[CH:8][CH:7]=4)[C:4]=2[CH:3]=1.I([O-])(=O)(=O)=O.[Na+]>C(O)C>[CH3:1][C:2]1[CH:15]=[CH:14][C:13]2[CH:12]([CH:16]=[O:19])[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[CH:5]([CH:17]=[O:18])[C:4]=2[CH:3]=1

Participants

4

Reactant 2

HCID 23667635Sodium periodateHCID 54099475HCID 54099475, compound

Product 1

HCID 23329598HCID 23329598, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A 2.5 g. portion of cis-2-methyl-9,10-dihydro-9,10-ethanoanthracene-11,12-diol [obtained above as yellow crystals (m.p. 227°-228° C.)] is suspended in 100 ml. of an aqueous solution containing 2.14 g. of sodium periodate and one ml. of ethanol. The mixture is stirred at room temperature for 2 hours and the solid is collected by filtration, washed with water and dried giving the desired product as a pale yellow solid, m.p. 125°-126° C.

Workup

  1. additionof an aqueous solution containing 2.14 g
  2. filtrationthe solid is collected by filtration
  3. washwashed with water
  4. customdried

Sources & evidence

ORD record
ord-db6ac7bea6ee4221919cbfaecc5f43ce
Source dataset
uspto-grants-1980_11
Patent number
US04235996

Reaction notes

Loading…