Benzyl Bromide → HCID 19746266, compound

HRID 2253727Notes

Reaction equation

HRID 2253727 reaction equation
C(Br)C1C=CC=CC=1.C(Br)CC1C=CC=CC=1.C(Br)C=CC1C=CC=CC=1.[C:28]([CH2:32][C:33]1[CH:38]=[C:37]([O:39][CH2:40][C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=2)[CH:36]=[C:35]([CH2:47][C:48]([O:50]C)=[O:49])[CH:34]=1)([O:30]C)=[O:29].[C:52]([CH2:56][C:57]1[CH:62]=[C:61]([O:63][CH2:64][CH2:65][C:66]2[CH:71]=[CH:70][CH:69]=[CH:68][CH:67]=2)[CH:60]=[C:59]([CH2:72][C:73]([O:75]C)=[O:74])[CH:58]=1)([O:54]C)=[O:53]>>[C:48]([CH2:47][C:35]1[CH:36]=[C:37]([O:39][CH2:40][C:41]2[CH:42]=[CH:43][CH:44]=[CH:45][CH:46]=2)[CH:38]=[C:33]([CH2:32][C:28]([OH:30])=[O:29])[CH:34]=1)([OH:50])=[O:49].[C:73]([CH2:72][C:59]1[CH:60]=[C:61]([O:63][CH2:64][CH2:65][C:66]2[CH:71]=[CH:70][CH:69]=[CH:68][CH:67]=2)[CH:62]=[C:57]([CH2:56][C:52]([OH:54])=[O:53])[CH:58]=1)([OH:75])=[O:74]

Participants

7

Reactant 5

HCID 7498Benzyl BromideHCID 7666Phenethyl bromideHCID 98116BromomethylstyreneHCID 19746283HCID 19746283, compoundHCID 19746287HCID 19746287, compound

Product 2

HCID 19746266HCID 19746266, compoundHCID 19746277HCID 19746277, compound

Procedure

When the procedure of Example 1 is followed and benzyl bromide or phenethyl bromide are used in place of cinnamylbromide in Step G, then the products prepared are 1,3-di-(carbomethoxymethyl)-5-benzyloxybenzene and 1,3-di-(carbomethoxymethyl)-5-phenethyloxybenzene. These compounds are hydrolyzed in the same manner as Example 1, Step H to obtain 1,3-di-(carboxymethyl)-5-benzyloxybenzene and 1,3-di-(carboxymethyl)-5-phenethyloxybenzene.

Workup

  1. customthe products prepared

Sources & evidence

ORD record
ord-7b4d64dc68864eb5a2ea9556d7b2baae
Source dataset
uspto-grants-1993_08
Patent number
US05232948

Reaction notes

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