Water → HCID 86612199, compound

HRID 225404Notes

Reaction equation

HRID 225404 reaction equation
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[S:9]([O:14]C)([O:12][CH3:13])(=[O:11])=[O:10].O>C(OCC)C>[S:9]([O-:14])([O-:12])(=[O:11])=[O:10].[CH3:8][S+:7]([CH3:13])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:8][S+:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH3:13]

Participants

5

Reactant 3

HCID 962WaterHCID 6497Dimethyl SulfateHCID 7520Thioanisole

Product 1

HCID 86612199HCID 86612199, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

6.2 g (0.05 mole) of thioanisole and 6.9 g (0.055 mole) of dimethyl sulfate were stirred for 12 hours at room temperature. 100 g of water and 50 ml of diethyl ether were added to the reaction solution whereupon the mixture separated into two layers. The aqueous layer was taken out, which was an aqueous solution of the target compound, dimethylphenylsulfonium sulfate.

Workup

  1. customseparated into two layers

Sources & evidence

ORD record
ord-ea8c19d0e5e54c419d16d402346fc712
Source dataset
uspto-grants-2009_07
Patent number
US07556909B2

Reaction notes

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