Ammonia → Benzenesulfinamide

HRID 2254186Notes

Reaction equation

HRID 2254186 reaction equation
[C:1]1([S:7](Cl)=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[NH3:10]>CCOCC>[C:1]1([S:7]([NH2:10])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 222AmmoniaHCID 4190003Benzenesulfinyl chloride

Product 1

HCID 11286519BenzenesulfinamideYield 17%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Benzenesulphinamide was prepared by reacting benzenesulphinyl chloride with ammonia in ether initially at -78° C. and finally at ambient temperature and was isolated in 17% yield as a solid, m.p. 112°-115° C.

Workup

  1. custominitially at -78° C.
  2. customfinally at ambient temperature and was isolated in 17% yield as a solid, m.p. 112°-115° C.

Sources & evidence

ORD record
ord-7fde7ad63c354631961f5d5b81c9d6fb
Source dataset
uspto-grants-1993_08
Patent number
US05234942

Reaction notes

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