Carbon Tetrachloride → HCID 19745066, compound

HRID 2254314Notes

Reaction equation

HRID 2254314 reaction equation
[Cl:1][Si:2]([Cl:9])([Cl:8])[CH2:3][Si:4]([Cl:7])([Cl:6])[CH3:5].C(Cl)(Cl)(Cl)[Cl:11]>CC(N=NC(C#N)(C)C)(C#N)C>[Cl:1][Si:2]([Cl:9])([Cl:8])[CH2:3][Si:4]([Cl:7])([Cl:6])[CH2:5][Cl:11]

Participants

4

Reactant 2

HCID 5943Carbon TetrachlorideHCID 126086481,1,1,3,3-Pentachloro-1,3-disilabutane

Product 1

HCID 19745066HCID 19745066, compound

Reagents, catalysts & solvents 1

HCID 6547AzobisisobutyronitrileSolvent

Procedure

120 g (0.46 mole) of 1,1,1,3,3-pentachloro-1,3-disilabutane and 1.2 g of a reaction initiator, AIBN in carbon tetrachloride as solvent were reacted in the same apparatus as Example 10. The obtained reactant was photoreacted for 12 hrs using sun lamp, while bubbling chlorine gas and refluxing carbon tetrachloride. The produced reaction mixture was distilled under vacuum to obtain 32 g of 1,1,1,3,3,4-hexachloro-1,3-disilabutane.

Workup

  1. customwhile bubbling chlorine gas
  2. temperaturerefluxing carbon tetrachloride
  3. customThe produced reaction mixture
  4. distillationwas distilled under vacuum

Sources & evidence

ORD record
ord-1d4fc93727654425a662c28f11f46768
Source dataset
uspto-grants-1993_08
Patent number
US05235061

Reaction notes

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