HCID 12054777, compound → HCID 86747098, compound

HRID 2254340Notes

Reaction equation

HRID 2254340 reaction equation
[Cl-].[Cl-].[CH2:3]([Ga+2:5])[CH3:4].[CH3:6][N-:7][CH2:8][CH2:9][N-:10][CH3:11].[Li+].[Li+]>CCCCCC>[CH3:6][N:7]1[CH2:8][CH2:9][N:10]([CH3:11])[Ga:5]1[CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 12054777HCID 12054777, compoundHCID 178461621HCID 178461621, compound

Product 1

HCID 86747098HCID 86747098, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent2×

Procedure

25.5 g (0.15 mol) of ethylgallium dichloride in 100 ml of n-hexane are added, at -20°, to 14.6 g (0.15 mol) of dilithium N,N'-dimethylethylenediamide in 300 ml of n-hexane. The mixture is stirred at room temperature for 2 hours and filtered, and the filtrate is concentrated. Sublimation at a bath temperature of 220° and a vacuum of 10-1 mbar gives 2,5-dimethyl-1-ethyl-2,5-diaza-1-gallacyclopentane as a colourless solid, stable in air. ##STR8##

Workup

  1. filtrationfiltered
  2. concentrationthe filtrate is concentrated

Sources & evidence

ORD record
ord-8b7203eddb8a4c37a0ad4110f42dd9be
Source dataset
uspto-grants-1993_08
Patent number
US05235078

Reaction notes

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