HCID 12054777, compound → HCID 86747098, compound

Participants

Reaction Steps

25.5 g (0.15 mol) of ethylgallium dichloride in 100 ml of n-hexane are added, at -20°, to 14.6 g (0.15 mol) of dilithium N,N'-dimethylethylenediamide in 300 ml of n-hexane. The mixture is stirred at room temperature for 2 hours and filtered, and the filtrate is concentrated. Sublimation at a bath temperature of 220° and a vacuum of 10-1 mbar gives 2,5-dimethyl-1-ethyl-2,5-diaza-1-gallacyclopentane as a colourless solid, stable in air. ##STR8##

Provenance & Evidence