1,10-Decanediamine → HCID 19742684, compound

HRID 2254531Notes

Reaction equation

HRID 2254531 reaction equation
[NH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][NH2:12].[CH2:13]([O:15]C=O)C>C(O)C>[NH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][NH:12][CH:13]=[O:15]

Participants

4

Reactant 2

HCID 13171,10-DecanediamineHCID 8025Ethyl formate

Product 1

HCID 19742684HCID 19742684, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

1,10-diaminodecane (6.88 g, 40 mmol) were dissolved in 100 ml of ethanol and 3.22 ml of ethylformate was added. The reaction mixture was stirred at room temperature under a nitrogen atmosphere for 18 hours and evaporated to dryness. The residue was chromatographed on a silica gel column using 25% methanol/methylenechloride as the eluent to obtain 4 g of the title product.

Workup

  1. customevaporated to dryness
  2. customThe residue was chromatographed on a silica gel column

Sources & evidence

ORD record
ord-9b2bc3c66c61494794afc2f2f0632dd5
Source dataset
uspto-grants-1993_08
Patent number
US05236900

Reaction notes

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