Methyl p-toluenesulfonate → HCID 14962390, compound

HRID 2254677Notes

Reaction equation

HRID 2254677 reaction equation
[CH3:1][C:2]1[Se:3][C:4]2[CH:10]=[CH:9][C:8]([CH3:11])=[CH:7][C:5]=2[N:6]=1.[C:12]1([CH3:23])[CH:17]=[CH:16][C:15]([S:18]([O:21]C)(=[O:20])=[O:19])=[CH:14][CH:13]=1>C(Cl)(Cl)Cl>[C:12]1([CH3:23])[CH:13]=[CH:14][C:15]([S:18]([O-:21])(=[O:19])=[O:20])=[CH:16][CH:17]=1.[CH3:1][C:2]1[Se:3][C:4]2[CH:10]=[CH:9][C:8]([CH3:11])=[CH:7][C:5]=2[N+:6]=1[CH3:12]

Participants

4

Reactant 2

HCID 6645Methyl p-toluenesulfonateHCID 5203682818-89-5

Product 1

HCID 14962390HCID 14962390, compoundYield 183.1%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Into a sealed tube were placed 4.20 g (20.0 mmoles) of 2,5-dimethylbenzoselenazole, 3.90 g (21.0 mmoles) of methyl paratoluenesulfonate and 20 ml of chloroform. A reaction and treatment were conducted by the same procedure as in Reference Example 4, giving 7.62 g (yield: 96%) of 2,3,5-trimethylbenzoselenazolium paratoluenesulfonate as a pink powder.

Workup

  1. customInto a sealed tube were placed
  2. customA reaction and treatment

Sources & evidence

ORD record
ord-9a543c1ba6154bab92fb1ebd8dbb95e8
Source dataset
uspto-grants-1993_08
Patent number
US05236958

Reaction notes

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