m-Chloroperbenzoic acid → HCID 19938675, compound

HRID 2255248Notes

Reaction equation

HRID 2255248 reaction equation
[F:1][C:2]1[CH:16]=[CH:15][C:5]([CH2:6][CH:7]2[C:11](=[CH2:12])[C:10]([CH3:14])([CH3:13])[CH2:9][CH2:8]2)=[CH:4][CH:3]=1.ClC1C=CC=C(C(OO)=[O:25])C=1.[OH-].[Ca+2].[OH-]>C(Cl)(Cl)Cl>[F:1][C:2]1[CH:16]=[CH:15][C:5]([CH2:6][CH:7]2[C:11]3([O:25][CH2:12]3)[C:10]([CH3:13])([CH3:14])[CH2:9][CH2:8]2)=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 70297m-Chloroperbenzoic acidHCID 6093208Calcium HydroxideHCID 19938670HCID 19938670, compound

Product 1

HCID 19938675HCID 19938675, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Into 170 ml of chloroform, 17 g of 5-(4-fluorobenzyl)-2,2-dimethyl-1-methylenecyclopentane (the compound No. 124 shown in Table 3) were dissolved, and then, 27.1 g of m-chloroperbenzoic acid were added to the mixture within 10 min, and the thus obtained mixture was stirred for 2 hours at room temperature. In the next place, 25.4 g of calcium hydroxide were added to the mixture within 10 min, and the mixture was stirred for 30 min at room temperature.

Workup

  1. dissolutionwere dissolved
  2. stirringthe mixture was stirred for 30 min at room temperature

Sources & evidence

ORD record
ord-7fd170f8e7eb4ef68c853648b25dc2ed
Source dataset
uspto-grants-1993_08
Patent number
US05239089

Reaction notes

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