Chloroform → HCID 19742157, compound

HRID 2255250Notes

Reaction equation

HRID 2255250 reaction equation
C(Cl)(Cl)Cl.[Cl:5][C:6]1[CH:20]=[CH:19][C:9]([CH2:10][CH:11]2[CH2:15][CH2:14][CH:13]([CH2:16][CH3:17])[C:12]2=[CH2:18])=[CH:8][CH:7]=1.ClC1C=CC=C(C(OO)=[O:29])C=1.[OH-].[Ca+2].[OH-]>O>[Cl:5][C:6]1[CH:20]=[CH:19][C:9]([CH2:10][CH:11]2[CH2:15][CH2:14][CH:13]([CH2:16][CH3:17])[C:12]32[O:29][CH2:18]3)=[CH:8][CH:7]=1

Participants

6

Reactant 4

HCID 6212ChloroformHCID 70297m-Chloroperbenzoic acidHCID 6093208Calcium HydroxideHCID 19742156HCID 19742156, compound

Product 1

HCID 19742157HCID 19742157, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Into 100 ml of chloroform, 8.0 g of 2-(4-chlorobenzyl)-5-ethyl-1-methylenecyclopentane (the compound No. 129 shown in Table 3) were dissolved, and then 11.6 g of m-chloroperbenzoic acid were added to the thus formed mixture within 5 min, and the whole mixture was stirred for 2 hours at room temperature. In the next place, 11 g of calcium hydroxide were added to the mixture under cooling with iced water, and the whole mixture was stirred for 30 min at room temperature.

Workup

  1. dissolutionwere dissolved
  2. stirringthe whole mixture was stirred for 30 min at room temperature

Sources & evidence

ORD record
ord-d107fc965dc34afcb5ef34dfe01f4237
Source dataset
uspto-grants-1993_08
Patent number
US05239089

Reaction notes

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