1,2-Dimethoxyethane → HCID 178521645, compound

HRID 2255871Notes

Reaction equation

HRID 2255871 reaction equation
[H-].[Al+3].[Li+].[H-].[H-].[H-].C[O:8][CH2:9][CH2:10][O:11][CH3:12]>>[CH2:10]1[O:11][CH2:12][C@@H:10]([OH:11])[C@H:9]([OH:8])[C@H:9]1[OH:8]

Participants

3

Reactant 2

HCID 80711,2-Dimethoxyethane2×HCID 21226445Aluminium lithium hydride

Product 1

HCID 178521645HCID 178521645, compound

Procedure

A stirred solution of 10.83 g of per-0-acetyl xylitol bromide in 30 ml of dry 1,2-dimethoxyethane was added dropwise to a stirred suspension of 13.0 g of lithium aluminum hydride in 200 ml of dry 1,2-dimethoxyethane kept under nitrogen at room temperature. After this processing, 3.34 g of 1,5-anhydroxylitol was obtained.

Workup

  1. customkept under nitrogen at room temperature

Sources & evidence

ORD record
ord-07239b3b01304b769114da928a7266f7
Source dataset
uspto-grants-1997_08
Patent number
US05654280

Reaction notes

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