Benzoyl Peroxide → HCID 22922984, compound

HRID 2257450Notes

Reaction equation

HRID 2257450 reaction equation
[CH3:1][C:2]1[C:3]([C:12](=[O:17])[C:13]([CH3:16])([CH3:15])[CH3:14])=[C:4]([CH:9]=[CH:10][CH:11]=1)[C:5]([O:7][CH3:8])=[O:6].[Br:18]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.C1(=O)NC(=O)CC1>C(Cl)(Cl)(Cl)Cl>[Br:18][CH2:1][C:2]1[C:3]([C:12](=[O:17])[C:13]([CH3:14])([CH3:16])[CH3:15])=[C:4]([CH:9]=[CH:10][CH:11]=1)[C:5]([O:7][CH3:8])=[O:6]

Participants

6

Reactant 4

HCID 7187Benzoyl PeroxideHCID 11439SuccinimideHCID 67184N-bromobutanimideHCID 22922977HCID 22922977, compound

Product 1

HCID 22922984HCID 22922984, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

A mixture of methyl 3-methyl-2-(2,2-dimethylpropanoyl)benzoate, N-bromosuccinimide and benzoylperoxide in of anhydrous carbon tetrachloride is stirred at reflux for about 1.5 hours. After cooling to room temperature the formed succinimide is collected by suction and washed with cold carbon tetrachloride. The mother liquors are evaporated to dryness in vacuo and the residue is rinsed with diethyl ether and collected by suction filtration to provide the title compound.

Workup

  1. temperatureat reflux for about 1.5 hours
  2. customis collected by suction
  3. washwashed with cold carbon tetrachloride
  4. customThe mother liquors are evaporated to dryness in vacuo
  5. washthe residue is rinsed with diethyl ether
  6. filtrationcollected by suction filtration

Sources & evidence

ORD record
ord-9351640a86684d0485dc7dc4ce1890a8
Source dataset
uspto-grants-1997_08
Patent number
US05658587

Reaction notes

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