8-Hydroxyquinoline → HCID 1422298, compound

HRID 2260018Notes

Reaction equation

HRID 2260018 reaction equation
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1F)([O-:3])=[O:2].[OH:14][C:15]1[CH:16]=[CH:17][CH:18]=[C:19]2[C:24]=1[N:23]=[CH:22][CH:21]=[CH:20]2.C(N(CC)CC)C>CC(C)=O>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[O:14][C:15]1[CH:16]=[CH:17][CH:18]=[C:19]2[C:24]=1[N:23]=[CH:22][CH:21]=[CH:20]2)([O-:3])=[O:2]

Participants

5

Reactant 3

HCID 19238-HydroxyquinolineHCID 6264DinitrofluorobenzeneHCID 8471Triethylamine

Product 1

HCID 1422298HCID 1422298, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

D. Reinheimer, et al, disclose (J. Org. Chem., 1957, vol. 22, p. 1743) that 2,4-dinitrofluorobenzene reacts with 8-hydroxyquinoline in acetone, in the presence of triethylamine, to form 8-(2,4-dinitrophenoxy)quinoline.

Sources & evidence

ORD record
ord-6562e18ecd16430381ef63e424367219
Source dataset
uspto-grants-1995_12
Patent number
US05475149

Reaction notes

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