Sodium Bicarbonate → HCID 22168674, compound

HRID 2260773Notes

Reaction equation

HRID 2260773 reaction equation
[CH2:1]([O:4][C:5]1[CH:16]=[CH:15][C:14]([N+:17]([O-])=O)=[CH:13][C:6]=1[C:7]([O:9][CH2:10][CH:11]=[CH2:12])=[O:8])[CH:2]=[CH2:3].C([O-])(O)=O.[Na+]>CO>[CH2:1]([O:4][C:5]1[CH:16]=[CH:15][C:14]([NH2:17])=[CH:13][C:6]=1[C:7]([O:9][CH2:10][CH:11]=[CH2:12])=[O:8])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 516892Sodium BicarbonateHCID 22168559HCID 22168559, compound

Product 1

HCID 22168674HCID 22168674, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Reduction of the above nitro compound by the method of Example 2, except that the solvent was methanol, and NaHCO3 solution was used to basify, gave allyl 2-allyloxy-5-aminobenzoate. Nmr (CDCl3): δ3.23 (br, 2H); 4.53 (dt, 2H); 4.79 (d, 2H); 5.21-5.49 (m, 4H); 5.93-6.14 (m, 2H); 6.80 (m, 2H); 7.16 (d, 1H).

Sources & evidence

ORD record
ord-6bd9cf5fdb5b4b4dac9cd913ceacfeb2
Source dataset
uspto-grants-1995_12
Patent number
US05478820

Reaction notes

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