1H-Pyrrolo(2,3-b)pyridine → HCID 178526243, compound

HRID 2261615Notes

Reaction equation

HRID 2261615 reaction equation
[NH:1]1[C:5]2=[N:6][CH:7]=[CH:8][CH:9]=[C:4]2[CH:3]=[CH:2]1.ClC1C=C(C=CC=1)C(OO)=[O:15]>ClCCl>[NH:1]1[C:5]2=[N+:6]([O-:15])[CH:7]=[CH:8][CH:9]=[C:4]2[CH:3]=[CH:2]1

Participants

4

Reactant 2

HCID 92221H-Pyrrolo(2,3-b)pyridineHCID 70297m-Chloroperbenzoic acid

Product 1

HCID 178526243HCID 178526243, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

1H-Pyrrolo[2,3-b]pyridine 7-oxide 507 is prepared by reacting 7-azaindole 1 with an oxidizing agent (e.g. m-chloro-peroxybenzoic acid) in an appropriate solvent (e.g. dichloromethane). After stirring at room temperature for 30 minutes to one hour, compound 507 is collected by filtration.

Workup

  1. filtrationcompound 507 is collected by filtration

Sources & evidence

ORD record
ord-3688e3bdc05842019d0bb87da52ce8d6
Source dataset
uspto-grants-2010_12
Patent number
US07846941B2

Reaction notes

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